Issue 40, 2016

Group 5 chemistry supported by β-diketiminate ligands

Abstract

β-Diketiminate (BDI) ligands are widely used supporting ligands in modern organometallic chemistry and are capable of stabilizing various metal complexes in multiple oxidation states and coordination environments. This review describes recent advances in the chemistry of group 5 metals, namely vanadium, niobium and tantalum supported by the BDI ligand framework. Special emphasis is put on the reactivity of low-valent complexes, as well as low-coordinate complexes containing reactive multiply bonded groups, such as alkylidene, imido and nitrido groups.

Graphical abstract: Group 5 chemistry supported by β-diketiminate ligands

Article information

Article type
Perspective
Submitted
12 พ.ค. 2559
Accepted
10 มิ.ย. 2559
First published
21 มิ.ย. 2559

Dalton Trans., 2016,45, 15725-15745

Group 5 chemistry supported by β-diketiminate ligands

S. Hohloch, B. M. Kriegel, R. G. Bergman and J. Arnold, Dalton Trans., 2016, 45, 15725 DOI: 10.1039/C6DT01770C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements