Issue 24, 2016

Insertion of tBuNC into thorium–phosphorus and thorium–arsenic bonds: phosphaazaallene and arsaazaallene moieties in f element chemistry

Abstract

The reactivity of thorium–phosphido and thorium–arsenido bonds was probed using tert-butyl isocyanide, tBuNC. Reaction of (C5Me5)2Th[E(H)R]2, E = P, As; R = 2,4,6-iPr3C6H2, 2,4,6-Me3C6H2 with tBuNC affords the first phosphaazaallene and arsaazaallene moieties with an f-element.

Graphical abstract: Insertion of tBuNC into thorium–phosphorus and thorium–arsenic bonds: phosphaazaallene and arsaazaallene moieties in f element chemistry

Supplementary files

Article information

Article type
Paper
Submitted
26 ก.พ. 2559
Accepted
13 เม.ย. 2559
First published
28 เม.ย. 2559
This article is Open Access
Creative Commons BY license

Dalton Trans., 2016,45, 10042-10049

Insertion of tBuNC into thorium–phosphorus and thorium–arsenic bonds: phosphaazaallene and arsaazaallene moieties in f element chemistry

A. C. Behrle and J. R. Walensky, Dalton Trans., 2016, 45, 10042 DOI: 10.1039/C6DT00776G

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