Issue 58, 2016

Synthesis of high molecular weight polyethylene using iminopyridyl nickel catalysts

Abstract

A series of iminopyridyl Ni(II) catalysts containing both the dibenzhydryl and the naphthyl moieties can polymerize ethylene with high activity and high thermal stability, generating polyethylene with a molecular weight of up to one million. In α-olefin polymerization, semicrystalline polymers with high melting temperatures are generated.

Graphical abstract: Synthesis of high molecular weight polyethylene using iminopyridyl nickel catalysts

Supplementary files

Article information

Article type
Communication
Submitted
17 ม.ค. 2559
Accepted
14 มี.ค. 2559
First published
14 มี.ค. 2559

Chem. Commun., 2016,52, 9113-9116

Synthesis of high molecular weight polyethylene using iminopyridyl nickel catalysts

S. Dai, X. Sui and C. Chen, Chem. Commun., 2016, 52, 9113 DOI: 10.1039/C6CC00457A

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