Issue 24, 2024

One-pot fabrication of vanadium-doped ordered mesoporous zirconium oxophosphate catalyst for the synthesis of carbonyl compounds

Abstract

Carbonyl compounds serve as essential raw materials in the production of fine chemicals and pharmaceuticals. An economical and environmentally-friendly route to generating carbonyl compounds involves the catalytic oxidation of alcohols and hydrocarbons using heterogeneous catalysts. In this work, we synthesize a series of vanadium-doped ordered mesoporous zirconium oxophosphate (V/M-ZrPO) nanocomposites via a modified one-pot evaporation-induced self-assembly approach. Characterization results confirm the successful embedding of vanadium species into the framework of the M-ZrPO support. Dispersion of vanadium sites generates catalysts exhibiting enhanced performance for the selective oxidation of alcohols and hydrocarbons to carbonyl compounds. In particular, the 20 V/M-ZrPO catalyst demonstrates excellent reusability and broad substrate compatibility. Relative to established catalytic materials, the 20 V/M-ZrPO catalyst demonstrated superior performance across key metrics including product yield, reaction time, and recyclability. These findings highlight the promise of V/M-ZrPO nanocomposites as efficient and durable catalysts for sustainable carbonyl compound production.

Graphical abstract: One-pot fabrication of vanadium-doped ordered mesoporous zirconium oxophosphate catalyst for the synthesis of carbonyl compounds

Article information

Article type
Paper
Submitted
11 เม.ย. 2567
Accepted
28 พ.ค. 2567
First published
28 พ.ค. 2567

New J. Chem., 2024,48, 10820-10829

One-pot fabrication of vanadium-doped ordered mesoporous zirconium oxophosphate catalyst for the synthesis of carbonyl compounds

W. Xu, H. Huang, L. Bi, H. Xu, Z. Miao and M. Wu, New J. Chem., 2024, 48, 10820 DOI: 10.1039/D4NJ01661K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements