Dual role tertiary amines in photocatalytic cyclizations: towards sustainable syntheses of 1,3-dinitrogen heterocycles

Abstract

A novel photocatalytic cascade has been engineered for the transformation of diketimines into 1,3-dinitrogen heterocycles, ingeniously repurposing methylamine a typically utilized sacrificial additive as a dual-function reagent, serving simultaneously as an electron donor and a methyl source. This innovation champions atom economy and underscores a commitment to sustainable chemical synthesis.

Graphical abstract: Dual role tertiary amines in photocatalytic cyclizations: towards sustainable syntheses of 1,3-dinitrogen heterocycles

Supplementary files

Article information

Article type
Communication
Submitted
22 ก.ค. 2567
Accepted
21 ส.ค. 2567
First published
22 ส.ค. 2567

Chem. Commun., 2024, Advance Article

Dual role tertiary amines in photocatalytic cyclizations: towards sustainable syntheses of 1,3-dinitrogen heterocycles

F. Guo, J. Zhu and X. Fan, Chem. Commun., 2024, Advance Article , DOI: 10.1039/D4CC03666B

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