Issue 58, 2017

A thermodynamic and kinetic analysis of solvent-enhanced selectivity in monophasic and biphasic reactor systems

Abstract

Selectivity control in biomass conversion is often realized by manipulating the solvent environment. Outcomes can be rationalized through a thermodynamically rigorous application of transition-state theory. We show that solvent-induced perturbations to selectivity in both monophasic and biphasic reactor systems are governed by the same underlying principles.

Graphical abstract: A thermodynamic and kinetic analysis of solvent-enhanced selectivity in monophasic and biphasic reactor systems

Supplementary files

Article information

Article type
Communication
Submitted
25 เม.ย. 2560
Accepted
26 มิ.ย. 2560
First published
27 มิ.ย. 2560

Chem. Commun., 2017,53, 8148-8151

A thermodynamic and kinetic analysis of solvent-enhanced selectivity in monophasic and biphasic reactor systems

T. J. Schwartz and J. Q. Bond, Chem. Commun., 2017, 53, 8148 DOI: 10.1039/C7CC03164E

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