Issue 63, 2024
From the journal:

Chemical Communications

Tuning the electronic properties of Zr UiO-66 through defect-functionalised multivariate modulation†

Carmen Rosales-Martínez, ORCID logo a   Marcelo Assis, ORCID logo *b   Celia Castillo-Blas ORCID logo *c  and  Isabel Abánades Lázaro ORCID logo *a  

* Corresponding authors

a Instituto de Ciencia Molecular, Universitat de Valencia, Calle catedrático José Beltrán Martínez, Paterna, Valencia, Spain
E-mail: isabel.abanades@uv.es

b Biomaterials and Bioengineering Lab, Translational Research Centre San Alberto Magno, Universidad Catolica de Valencia San Vicente Mártir (UCV), Spain

c Department of Materials Science and Metallurgy, 27 Charles Babbage road, University of Cambridge, Cambridge, UK

Abstract

The multivariate modulation of Metal–Organic Frameworks is presented as a valuable tool to introduce multiple functional units into UiO-66 while increasing its porosity. This manuscript encloses a comprehensive study using p-functionalised benzoate –NO2, –SO3 and –SH modulators, rationalizing the defects introduced and their impact on properties.

Graphical abstract: Tuning the electronic properties of Zr UiO-66 through defect-functionalised multivariate modulation

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Article information

DOI
https://doi.org/10.1039/D4CC02581D
Article type
Communication
Submitted
28 พ.ค. 2567
Accepted
05 ก.ค. 2567
First published
08 ก.ค. 2567
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2024,60, 8280-8283

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Tuning the electronic properties of Zr UiO-66 through defect-functionalised multivariate modulation

C. Rosales-Martínez, M. Assis, C. Castillo-Blas and I. Abánades Lázaro, Chem. Commun., 2024, 60, 8280 DOI: 10.1039/D4CC02581D

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