Issue 59, 2024

2D metal–organic frameworks bearing butterfly-shaped metal-bis(dithiolene) linkers from dithiol-functionalized benzenedicarboxylic acid

Abstract

An assembly between 1,4-dicarboxylbenzene-2,3-dithiol (H2dcbdt) and different transition metal ions successfully produced 2D metal–organic frameworks (M-dcbdt, M = Ni, Co or Fe) composed of unprecedented butterfly-shaped metal-bis(dithiolene) (MS4) linkers in one-pot fashion. Such strategy provides easier access to the [MS4]-rich network and lowers the prerequisite to explore their applications.

Graphical abstract: 2D metal–organic frameworks bearing butterfly-shaped metal-bis(dithiolene) linkers from dithiol-functionalized benzenedicarboxylic acid

Supplementary files

Article information

Article type
Communication
Submitted
10 พ.ค. 2567
Accepted
19 มิ.ย. 2567
First published
20 มิ.ย. 2567

Chem. Commun., 2024,60, 7578-7581

2D metal–organic frameworks bearing butterfly-shaped metal-bis(dithiolene) linkers from dithiol-functionalized benzenedicarboxylic acid

H. Zhong, Z. Jiang, J. Hu, L. Chung and J. He, Chem. Commun., 2024, 60, 7578 DOI: 10.1039/D4CC02282C

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