Isolated PdO sites on SiO2-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation

Aleksandra Ziarko; Thomas J. A. Slater; Mark A. Isaacs; Lee J. Durndell; Christopher M. A. Parlett

doi:10.1039/D3CY00198A

Isolated PdO sites on SiO₂-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation†‡

Aleksandra Ziarko,^a Thomas J. A. Slater,

^b Mark A. Isaacs,

^cd Lee J. Durndell

^e and Christopher M. A. Parlett

*^fghi

Author affiliations

* Corresponding authors

^a Department of Chemical Engineering and Applied Chemistry, Aston University, Birmingham, UK

^b School of Chemistry, Cardiff University, Cardiff, UK

^c Department of Chemistry, University College London, London, UK

^d HarwellXPS, Research Complex at Harwell, RAL, Harwell Campus, Didcot, UK

^e School of Geography, Earth and Environmental Sciences, University of Plymouth, Plymouth, UK

^f Department of Chemical Engineering, University of Manchester, Manchester, UK
E-mail: christopher.parlett@manchester.ac.uk

^g University of Manchester at Harwell, Diamond Light Source, Rutherford Appleton Laboratory, Didcot, Oxfordshire, UK

^h Diamond Light Source, Rutherford Appleton Laboratory, Didcot, Oxfordshire, UK

ⁱ UK Catalysis Hub, Research Complex at Harwell, Rutherford Appleton Laboratory, Oxfordshire, UK

Abstract

Catalytic allylic alcohol oxidation to aldehydes is an industrial process that necessitates chemoselectivity. Surface PdO (on Pd) enables this transformation but does not represent optimal metal utilisation. Here we report a facile synthesis route to produce isolated surface PdO catalytic sites on an earth-abundant metal (NiO) for cinnamyl alcohol oxidation.

This article is part of the themed collection: Oxidation for a Sustainable Future and Clean Environment

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Article information

DOI: https://doi.org/10.1039/D3CY00198A
Article type: Communication
Submitted: 11 ก.พ. 2566
Accepted: 11 พ.ค. 2566
First published: 12 พ.ค. 2566
This article is Open Access

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Catal. Sci. Technol., 2023,13, 3483-3488

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Isolated PdO sites on SiO₂-supported NiO nanoparticles as active sites for allylic alcohol selective oxidation

A. Ziarko, T. J. A. Slater, M. A. Isaacs, L. J. Durndell and C. M. A. Parlett, Catal. Sci. Technol., 2023, 13, 3483 DOI: 10.1039/D3CY00198A

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Catalysis Science & Technology