Dual C–H activation: Rh(III)-catalyzed cascade π-extended annulation of 2-arylindole with benzoquinone

Qijing Zhang; Qianrong Li; Chengming Wang

doi:10.1039/D1RA01779A

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Dual C–H activation: Rh(iii)-catalyzed cascade π-extended annulation of 2-arylindole with benzoquinone†

Qijing Zhang,‡^a Qianrong Li ‡^a and Chengming Wang

*^a

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* Corresponding authors

^a Department of Chemistry, College of Chemistry and Materials Science, Jinan University, Guangzhou, China
E-mail: cmwang2019@jnu.edu.cn

Abstract

A rhodium-catalyzed, N–H free indole directed cyclization reaction of benzoquinone via a dual C–H activation strategy is disclosed. This protocol has a good functional group tolerance and affords useful indole-fused heterocylces. Besides, it is insensitive to moisture, commercially available solvent can be directly used and work quite well for this transformation.

This article is part of the themed collection: Elegant Synthetic Routes to Indole Derivatives

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DOI: https://doi.org/10.1039/D1RA01779A
Article type: Paper
Submitted: 06 มี.ค. 2564
Accepted: 26 มี.ค. 2564
First published: 07 เม.ย. 2564
This article is Open Access

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RSC Adv., 2021,11, 13030-13033

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Dual C–H activation: Rh(III)-catalyzed cascade π-extended annulation of 2-arylindole with benzoquinone

Q. Zhang, Q. Li and C. Wang, RSC Adv., 2021, 11, 13030 DOI: 10.1039/D1RA01779A

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Dual C–H activation: Rh(iii)-catalyzed cascade π-extended annulation of 2-arylindole with benzoquinone†

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