Issue 2, 2020

Engineering orthogonality in the construction of an alternating rhomboidal copolymer with high fidelity via integrative self-sorting

Abstract

Microtubules play versatile roles in vital movements due to their unique structures in which the subunits α-tubulin and β-tubulin show a strictly alternating arrangement. The synthesis of artificial copolymers with an alternating arrangement has drawn much research attention. However, as far as we know, an alternating copolymer constructed from monomers with complicated self-assembled structures is still rarely reported. Herein, an alternating rhomboidal copolymer (ARC) with high fidelity was prepared by multicomponent self-assembly in one pot based on metal-coordination and host–guest interactions. The delicate structure of the copolymer benefits from the combination of orthogonal self-assembly and integrative self-sorting strategies. Orthogonal self-assembly guarantees the copolymer with a hierarchical structure that rhomboidal metallacycles maintain their structure by metal–ligand coordination and link to each other through host–guest interactions. Meanwhile, integrative self-sorting endows the copolymer with an alternating arrangement based on different host–guest sites on the two rhomboidal metallacyclic cores. This work not only leads to an alternating rhomboidal copolymer having an intricate structure but also develops a strategy to construct novel supramolecular polymers with hierarchical complexity.

Graphical abstract: Engineering orthogonality in the construction of an alternating rhomboidal copolymer with high fidelity via integrative self-sorting

Supplementary files

Article information

Article type
Paper
Submitted
10 มิ.ย. 2562
Accepted
06 ส.ค. 2562
First published
06 ส.ค. 2562

Polym. Chem., 2020,11, 367-374

Engineering orthogonality in the construction of an alternating rhomboidal copolymer with high fidelity via integrative self-sorting

Z. Zhang, Y. Liu, J. Zhao and X. Yan, Polym. Chem., 2020, 11, 367 DOI: 10.1039/C9PY00848A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements