Issue 17, 2016

How does tetraphenylethylene relax from its excited states?

Abstract

Tetraphenylethylene is a prototypical example of a molecule displaying aggregation-induced emission. Despite many studies on the optical properties of TPE and its derivatives, the origin of the non-emissive behavior in the gas phase or in dilute solutions has yet to be unravelled. Here, we identify the ultrafast deactivation mechanisms responsible for the fluorescence quenching in isolated TPE.

Graphical abstract: How does tetraphenylethylene relax from its excited states?

Supplementary files

Article information

Article type
Communication
Submitted
31 ก.ค. 2558
Accepted
17 ก.ย. 2558
First published
17 ก.ย. 2558

Phys. Chem. Chem. Phys., 2016,18, 11606-11609

Author version available

How does tetraphenylethylene relax from its excited states?

A. Prlj, N. Došlić and C. Corminboeuf, Phys. Chem. Chem. Phys., 2016, 18, 11606 DOI: 10.1039/C5CP04546K

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