Issue 10, 2011
From the journal:

New Journal of Chemistry

A meta-xylenediamidemacrocycle containing rotaxane anion host system constructed by a new synthetic clipping methodology†‡

Nicholas H. Evans,a   Christopher J. Serpella  and  Paul D. Beer*a  

* Corresponding authors

a Department of Chemistry, Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, UK
E-mail: paul.beer@chem.ox.ac.uk

Abstract

A novel rotaxane containing a meta-xylenediamide macrocycle is prepared by a new clipping methodology. Upon anion metathesis to the non-coordinating hexafluorophosphate salt, the rotaxane host system was shown to bind chloride and bromide anions more strongly than the basic oxoanions dihydrogen phosphate and acetate in the competitive solvent system 1 : 1 CDCl3 : CD3OD.

Graphical abstract: A meta-xylenediamide macrocycle containing rotaxane anion host system constructed by a new synthetic clipping methodology

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1NJ20109C
Article type
Paper
Submitted
11 Feb 2011
Accepted
25 Mar 2011
First published
03 May 2011

New J. Chem., 2011,35, 2047-2053

Permissions

Request permissions

A meta-xylenediamide macrocycle containing rotaxane anion host system constructed by a new synthetic clipping methodology

N. H. Evans, C. J. Serpell and P. D. Beer, New J. Chem., 2011, 35, 2047 DOI: 10.1039/C1NJ20109C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements