Issue 2, 2010

Chiral bifunctional phase transfer catalysts for asymmetric fluorination of β-keto esters

Abstract

Chiral bifunctional phase transfer catalysts introducing bis(diarylhydroxymethyl) substituents at 3,3′-positions of the chiral binaphthyl core were successfully applied to asymmetric fluorination of cyclic β-keto esters with high enantioselectivities.

Graphical abstract: Chiral bifunctional phase transfer catalysts for asymmetric fluorination of β-keto esters

Supplementary files

Article information

Article type
Communication
Submitted
29 ก.ย. 2552
Accepted
13 พ.ย. 2552
First published
27 พ.ย. 2552

Chem. Commun., 2010,46, 321-323

Chiral bifunctional phase transfer catalysts for asymmetric fluorination of β-keto esters

X. Wang, Q. Lan, S. Shirakawa and K. Maruoka, Chem. Commun., 2010, 46, 321 DOI: 10.1039/B920099A

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