Issue 16, 2017

Catalytic carbonyl hydrosilylations via a titanocene borohydride–PMHS reagent system

Abstract

Reduction of a wide range of aldehydes and ketones with catalytic amounts of titanocene borohydride in concert with a stoichiometric poly(methylhydrosiloxane) (PMHS) reductant is reported. Preliminary mechanistic studies demonstrate that the reaction is mediated by a reactive titanocene(III) complex, whose oxidation state remains constant throughout the reaction.

Graphical abstract: Catalytic carbonyl hydrosilylations via a titanocene borohydride–PMHS reagent system

Supplementary files

Article information

Article type
Paper
Submitted
31 พ.ค. 2560
Accepted
01 ก.ค. 2560
First published
03 ก.ค. 2560

Catal. Sci. Technol., 2017,7, 3469-3473

Catalytic carbonyl hydrosilylations via a titanocene borohydride–PMHS reagent system

G. D. Fianu, K. C. Schipper and R. A. Flowers II, Catal. Sci. Technol., 2017, 7, 3469 DOI: 10.1039/C7CY01088E

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