Xuexiang Ma, Chao Shan, Tingting Zhang, Yusheng Liu, Aili Feng and Dongju Zhang
Catal. Sci. Technol., 2026, Advance Article
Abstract
DFT calculations clarify the mechanism of Pd/phosphine ligand/norbornene-catalyzed aryl chloride difunctionalization, rationalizing chemoselectivity and the roles of norbornene and XPhos ligand.
Samir P. Rezgui, Jonathan Farhi, Hao Yu, Zachary P. Sercel, Scott C. Virgil and Brian M. Stoltz
Chem. Sci., 2024,15, 12284-12290
From themed collection:
2024 Chemical Science HOT Article Collection
Abstract
Herein, we report a novel approach to pyrroloiminoquinones which was enabled by the development of a Larock/Buchwald–Hartwig annulation/cyclization cascade to rapidly construct the core, which was further elaborated to 5 of these natural products.
Giulia Brufani, Shaomin Chen, Maria Teresa Tiberi, Filippo Campana, Emilia Paone, Yanlong Gu, Francesco Mauriello and Luigi Vaccaro
Green Chem., 2025,27, 3869-3878
From themed collection:
2025 Green Chemistry Covers
Abstract
In this study, we present a waste-minimized strategy for synthesising diarylamines and triarylamines via Buchwald–Hartwig coupling.
Vladislav A. Voloshkin, Yaxu Liu, Marek Beliš, Min Peng, Kristof Van Hecke, Catherine S. J. Cazin and Steven P. Nolan
Dalton Trans., 2023,52, 3690-3698
Abstract
The synthesis and catalytic activity of novel phosphine palladium PEPPSI and dimer complexes bearing RuPhos, SPhos and XPhos phosphines is reported.
Yulia Ivanova, Sander Spittaels, Ling-Jie Gao, Dominique Schols, Luc Van Meervelt, Mathy Froeyen, Wim Dehaen and Steven De Jonghe
Org. Biomol. Chem., 2024,22, 7373-7389
Abstract
A novel route to various substituted isothiazolo[4,5-b]pyridines was established. The compounds completely lacked GAK affinity, which was explained by in silico analysis.