Probing the binding and activation of small molecules by gas-phase transition metal clustersviaIR spectroscopy

André Fielicke

Chem. Soc. Rev., 2023, 52, 3778
DOI: 10.1039/D2CS00104G

Direct reduction of NO into N2 catalyzed by fullerene-supported rhodium clusters

Ruomeng Li, Ya-Ke Li, Jianzhi Xu and Gao-Lei Hou

Phys. Chem. Chem. Phys., 2024, 26, 15332
DOI: 10.1039/D4CP01398K

Structure, spectra, and intracluster chemistry of gas-phase platinum nitrosyl ion–molecule complexes

Philip A. J. Pearcy, Edward I. Brewer, Gabriele Meizyte, Scott Harrington, Matthew Doll, Peter D. Watson, Christian T. Haakansson and Stuart R. Mackenzie

Phys. Chem. Chem. Phys., 2025, 27, 24256
DOI: 10.1039/D5CP03460D

Gas-phase reactions driven by polarized metal–metal bonding in atomic clusters

Xiao-Na Li and Sheng-Gui He

Phys. Chem. Chem. Phys., 2023, 25, 4444
DOI: 10.1039/D2CP05148F

Reactions of N2O and CO on neutral Rh10On clusters: a density functional study

Vikram Muman, Alex Tennyson-Davies, Oihan Allegret and Matthew A. Addicoat

Phys. Chem. Chem. Phys., 2024, 26, 2218
DOI: 10.1039/D3CP04929A

Mechanisms of catalytic NO reduction mediated by gas-phase metal clusters

Xin-Yue Sun, Zi-Han Wang and Xiao-Na Li

Phys. Chem. Chem. Phys., 2025, 27, 23517
DOI: 10.1039/D5CP03258J

Size-dependent catalytic reactivity of NO reduction by CO mediated by RhnV2O3− clusters (n = 2–5)

Jin-You Chen, Hai Zhu, Tong-Mei Ma and Xiao-Na Li

Dalton Trans., 2025, 54, 5017
DOI: 10.1039/D4DT03118K

Reverse water–gas shift catalyzed by RhnVO3,4− (n = 3–7) cluster anions under variable temperatures

An Zhao, Qing-Yu Liu, Zi-Yu Li, Xiao-Na Li and Sheng-Gui He

Dalton Trans., 2024, 53, 8347
DOI: 10.1039/D4DT00541D

NO Dissociation on Platinum and Platinum-Rhodium Alloy: A Theoretical Investigation

Khanh Bao Vu, Khoa Thanh Phung, Le Hoang Thong, Bui Thi Linh and Nguyen Ngoc Huyen

Bull. Chem. React. Eng. Catal., 2024, 19, 32
DOI: 10.9767/bcrec.20070

Size-Dependent Reactivity of Con– (n = 5–25) Cluster Anions toward Carbon Dioxide

Xing-Yue He, Yun-Zhu Liu, Jiao-Jiao Chen, Xingwang Lan, Xiao-Na Li and Sheng-Gui He

J. Phys. Chem. Lett., 2023, 14, 6948
DOI: 10.1021/acs.jpclett.3c01478

Selective Reduction of NO into N2 Catalyzed by the RhM2O3– Clusters (M = Ta, V, and Al): Importance of the Triatomic Lewis Acid–Base–Acid Mδ+–Rhδ––Mδ+ Site

Jin-You Chen, Yi Liu, Tong-Mei Ma, Zi-Yu Li and Xiao-Na Li

Inorg. Chem., 2024, 63, 19179
DOI: 10.1021/acs.inorgchem.4c02767

Synergistic Effects in the Activity of Nano‐Transition‐Metal Clusters Pt12M (M=Ir, Ru or Rh) for NO Dissociation

Jelle Vekeman, Qing Wang, Xavier Deraet, Dominique Bazin, Frank De Proft, Hazar Guesmi and Frederik Tielens

ChemPhysChem, 2022, 23
DOI: 10.1002/cphc.202200374

Development of a Master Equation‐Based Microkinetic Model to Investigate Gas Phase Cluster Reactions Across a Wide Pressure and Temperature Range

Máté Szalay and Tibor Höltzl

ChemPhysChem, 2025, 26
DOI: 10.1002/cphc.202400465

High-temperature reactivity of vanadium oxide clusters in methane activation: Vibrational degrees of freedom matter

Man Ruan, Yan-Xia Zhao, Gong-Ping Wei and Sheng-Gui He

The Journal of Chemical Physics, 2023, 158
DOI: 10.1063/5.0148304

Boosting N2 Selectivity of Catalytic NO Reduction via Single-Atom Engineered MTaO3– (M = Cu, Al, V, Ti, Nb, and Ce) Clusters

Xin-Yue Sun, Yi Liu, Rui Li and Xiao-Na Li

J. Phys. Chem. Lett., 2026
DOI: 10.1021/acs.jpclett.6c00552

A Single Copper–Vanadium Oxide Cluster Cu3VO3– Reduces Four NO Molecules with the Accomplishment of a Catalytic Cycle by CO

Si-Dun Wang, Xin-Yue Sun, Zi-Han Wang, Tong-Mei Ma, Sheng-Gui He and Xiao-Na Li

J. Phys. Chem. Lett., 2025, 16, 13215
DOI: 10.1021/acs.jpclett.5c03457

NO Bond Cleavage on Gas-Phase Irn+ Clusters Investigated by Infrared Multiple Photon Dissociation Spectroscopy

Masato Yamaguchi, Yufei Zhang, Olga V. Lushchikova, Joost M. Bakker and Fumitaka Mafuné

J. Phys. Chem. A, 2022, 126, 6668
DOI: 10.1021/acs.jpca.2c05029

Catalytic NO_x Aftertreatment—Towards Ultra-Low NO_x Mobility

Navjot Sandhu, Xiao Yu and Ming Zheng

IJAMM, 2024, 4
DOI: 10.53941/ijamm.2024.100004

Role of H2O Adsorption in CO Oxidation over Cerium-Oxide Cluster Anions (CeO2)nO– (n = 1–4)

Jiao-Jiao Chen, Si-Dun Wang, Xun-Lei Ding and Sheng-Gui He

J. Phys. Chem. Lett., 2024, 15, 9078
DOI: 10.1021/acs.jpclett.4c02045

Catalytic NO Reduction by Noble-Metal-Free Vanadium–Aluminum Oxide Cluster Anions

Si-Dun Wang, Jiao-Jiao Chen, Tong-Mei Ma, Xiao-Na Li and Sheng-Gui He

J. Phys. Chem. Lett., 2023, 14, 4388
DOI: 10.1021/acs.jpclett.3c00767

Supported and isolated metal atoms and clusters as models for understanding the hydrogen economy

Gao-Lei Hou and Ewald Janssens

Fundamental Research, 2026, 6, 201
DOI: 10.1016/j.fmre.2023.10.011

CO Oxidation Promoted by NO Adsorption on RhMn2O3– Cluster Anions

Si-Dun Wang, Tong-Mei Ma, Xiao-Na Li and Sheng-Gui He

J. Phys. Chem. A, 2024, 128, 738
DOI: 10.1021/acs.jpca.3c06445

C60-Supported Single Pt Atom for Selective CH4 Activation

Jiao-Jiao Chen, Xi-Guan Zhao, Bo-Han Zang, Hui-Ru Jia, Qing-Yu Liu, Xun-Lei Ding and Sheng-Gui He

J. Phys. Chem. Lett., 2025, 16, 6463
DOI: 10.1021/acs.jpclett.5c01340

Methane activation by closed-shell tantalum sulfide anions TaS3−

Qian Li, Xiao-Xiao Liu, Qing-Yu Liu and Sheng-Gui He

Chinese Journal of Chemical Physics, 2024, 37, 823
DOI: 10.1063/1674-0068/cjcp2407094

The reactivity of Tan+ clusters with NO molecules: N–O bond dissociation and NOx conversion

Ran Cheng, Yifan Gao and Zhixun Luo

The Journal of Chemical Physics, 2025, 163
DOI: 10.1063/5.0304869

Catalytic NO Reduction by NO Pre‐Adsorbed RhCeO2NO− Clusters

Jiao‐Jiao Chen, Qing‐Yu Liu, Si‐Dun Wang, Xiao‐Na Li and Sheng‐Gui He

ChemPhysChem, 2023, 24
DOI: 10.1002/cphc.202200743

Dual Conflicting Roles of Preattached CO in the Water–Gas Shift Reaction Mediated by Iridium–Vanadium Oxide Clusters IrV2O3,4CO–

Yi Liu, Sheng-Gui He and Xiao-Na Li

J. Phys. Chem. Lett., 2025, 16, 11649
DOI: 10.1021/acs.jpclett.5c02987

Selective Reduction of NO into N2 Catalyzed by Rh1-Doped Cluster Anions RhCe2O3–5–

Jiao-Jiao Chen, Si-Dun Wang, Zi-Yu Li, Xiao-Na Li and Sheng-Gui He

J. Am. Chem. Soc., 2023, 145, 18658
DOI: 10.1021/jacs.3c06565

Outstanding Features of Rhodium Clusters for Hydrogen Adsorption and Desorption Revealed by Thermal Desorption Spectrometry

Fumitaka Mafuné, Hayato Kurashita, Satoshi Kudoh, Ken Miyajima, Masato Yamaguchi and Toshiaki Nagata

J. Phys. Chem. A, 2025, 129, 6236
DOI: 10.1021/acs.jpca.5c02121

An Infrared Spectroscopic Investigation of Nitric Oxide Binding on Isolated Cobalt Cluster Cations

Peter T. Rubli, Christian T. Haakansson, Philip A. J. Pearcy, Ruby G. Spratt, Joost M. Bakker, Peter D. Watson and Stuart R. Mackenzie

J. Phys. Chem. A, 2025, 129, 5810
DOI: 10.1021/acs.jpca.5c02939

A Combined Infrared and Computational Study of Gas-Phase Mixed-Ligand Rhodium Complexes: Rh(CO)n(N2O)m+ (n = 1–5, m = 1–4)

Gabriele Meizyte, Rachael H. Brown, Edward I. Brewer, Peter D. Watson and Stuart R. Mackenzie

J. Phys. Chem. A, 2023, 127, 9220
DOI: 10.1021/acs.jpca.3c05078

Mechanism of water molecule dissociation on transition metal cluster surfaces based on density functional theory

Kai Diao, Wenlei Cao, Xia Qiu, Mei Yang, Shunping Shi and Deliang Chen

Journal of Molecular Liquids, 2025, 428, 127491
DOI: 10.1016/j.molliq.2025.127491

What Determines the Drastic Reactivity of Nbn+ Clusters with Nitric Oxide under Thermalized Conditions?

Benben Huang, Wen Gan, Klavs Hansen and Zhixun Luo

J. Phys. Chem. A, 2022, 126, 4801
DOI: 10.1021/acs.jpca.2c03977

Catalytic NO Reduction by Single Au-Doped Aluminum Oxide Cluster Anions: Structural Role of Au

Hui-Ru Jia, Yu-Zhe Hu, Jiao-Jiao Chen, Jun Ma, Xun-Lei Ding and Sheng-Gui He

J. Phys. Chem. Lett., 2026, 17, 3954
DOI: 10.1021/acs.jpclett.6c00383

Adsorption Forms of NO Molecules Adsorbed on Surfaces of Gas-Phase Metal Clusters Investigated by Infrared Multiple Photon Dissociation Spectroscopy

Toshiaki NAGATA and Fumitaka MAFUNÉ

Vac. Surf. Sci., 2023, 66, 337
DOI: 10.1380/vss.66.337

Factors Determining the Selectivity of NO Reduction Catalyzed by Copper‐Vanadium Oxide Cluster Anions Cu2VO3−5−

Si‐Dun Wang, Yi Liu, Tong‐Mei Ma, Xiao‐Na Li and Sheng‐Gui He

ChemPhysChem, 2025, 26
DOI: 10.1002/cphc.202400888

An Infrared Study of Gas-Phase Metal Nitrosyl Ion–Molecule Complexes

Gabriele Meizyte, Philip A. J. Pearcy, Peter D. Watson, Edward I. Brewer, Alice E. Green, Matthew Doll, Olga A. Duda and Stuart R. Mackenzie

J. Phys. Chem. A, 2022, 126, 9414
DOI: 10.1021/acs.jpca.2c07228