Issue 19, 2023

Comparing the reactivity of an oxoiron(iv) cation radical and its oxoiron(v) tautomer towards C–H bonds

Abstract

An oxoiron(IV) cation radical is generated upon two-electron oxidation of an iron(III) complex bearing an electron-rich methoxy substituted bTAML framework and thoroughly characterized via multiple spectroscopic techniques and density functional theory (DFT). Reactivity studies demonstrate faster rates for oxidation of strong aliphatic sp3 C–H bonds than for its corresponding oxoiron(V) valence tautomer.

Graphical abstract: Comparing the reactivity of an oxoiron(iv) cation radical and its oxoiron(v) tautomer towards C–H bonds

Supplementary files

Article information

Article type
Communication
Submitted
23 டிசம்பர் 2022
Accepted
07 பிப்ரவரி 2023
First published
13 பிப்ரவரி 2023

Chem. Commun., 2023,59, 2755-2758

Comparing the reactivity of an oxoiron(IV) cation radical and its oxoiron(V) tautomer towards C–H bonds

S. Jana, S. Pattanayak, S. Das, M. Ghosh, L. Velasco, D. Moonshiram and S. Sen Gupta, Chem. Commun., 2023, 59, 2755 DOI: 10.1039/D2CC07005G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements