Issue 74, 2022

Sodium storage mechanism of a GeP5/C composite as a high capacity anode material for sodium-ion batteries

Abstract

The sodium storage mechanism of a GeP5/C composite electrode was revealed. Metallic Ge formed during discharge enhances the electronic conductivity of the electrode, while NaxP mitigates the agglomeration and volume change of Ge in the alloying process. The GeP5 phase is regenerated after recharge along with elemental Ge and P, implying a reversible phase transition of GeP5 during cycling.

Graphical abstract: Sodium storage mechanism of a GeP5/C composite as a high capacity anode material for sodium-ion batteries

Supplementary files

Article information

Article type
Communication
Submitted
05 ஜூலை 2022
Accepted
19 ஆகஸ்ட் 2022
First published
20 ஆகஸ்ட் 2022

Chem. Commun., 2022,58, 10345-10348

Sodium storage mechanism of a GeP5/C composite as a high capacity anode material for sodium-ion batteries

M. Zhang, J. Meng, N. Xiao, R. Shao, X. Wu, P. Gao, Z. Shadike and Y. Zhou, Chem. Commun., 2022, 58, 10345 DOI: 10.1039/D2CC03728A

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