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Abstract | Cited by

Literature casts einsteinium as a departure from earlier transplutonium actinides, with a decrease in stability constants with aminopolycarboxylate ligands. This report studies transplutonium chemistry – including Am, Bk, Cf, and Es – with aminopolycarboxylate ligands. Es complexation follows similar thermodynamic and structural trends established by the earlier actinides, consistent with first-principle calculations.

Graphical abstract: Revisiting complexation thermodynamics of transplutonium elements up to einsteinium

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