For the first time, an ionic liquid-mediated nickel-catalysed mild yet efficient protocol has been developed for biaryl synthesis via Suzuki–Miyaura cross coupling (SMC) reactions.
The interface engineering of CeO2/CoO with different spatial orientations modifies the electronic band structure, thereby stabilizing photogenerated charge carriers in the conduction band and improving photocatalytic SMC reaction under visible light.
PIII-doped heterosumanenes are synthesized to show diverse coordination patterns with transition metals. The coordination complexes with Pd2+ have been proved to be promising catalysts for the Suzuki–Miyaura coupling reaction of aryl chlorides.
A highly efficient catalytic system for the Suzuki–Miyaura reaction of deactivated and hindered aryl chlorides using trace amounts of commercial catalysts was reported.
Herein, we report a commercially available natural saponin acting as a surfactant and serving as a micellar catalyst, enabling Suzuki–Miyaura cross-coupling effectively with highly challenging heteroaromatic substrates in water at room temperature.