Seeded control of symmetry-directed diverse chiral π-stacked benzothiadiazole assemblies with leucine-based diamide units

Abstract

Symmetrical and unsymmetrical incorporation of leucine-derived diamides with identical chirality into a benzothiadiazole-containing aryleneethynylene enables seeded control of three distinct chiral π-stacked assemblies. Theoretical studies indicate that the orientation of benzothiadiazole units contributes to this diversity, highlighting how substitution patterns and kinetic control program structurally ordered complexity in π-conjugated supramolecular systems.

Graphical abstract: Seeded control of symmetry-directed diverse chiral π-stacked benzothiadiazole assemblies with leucine-based diamide units

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Article information

Article type
Communication
Submitted
30 Aug 2025
Accepted
30 Sep 2025
First published
01 Oct 2025

Chem. Commun., 2025, Advance Article

Seeded control of symmetry-directed diverse chiral π-stacked benzothiadiazole assemblies with leucine-based diamide units

S. Yamada, N. Inai, S. Ogi, T. Yanai and S. Yamaguchi, Chem. Commun., 2025, Advance Article , DOI: 10.1039/D5CC05008A

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