Issue 37, 2022

Sulfur-containing polymers derived from SO2: synthesis, properties, and applications

Abstract

Sulfur-containing polymers enjoy the merits of excellent optical performance, degradation, chemical recyclability, and adhesive abilities toward metal ions. Recently, increasing attention has been paid to the synthesis and applications of sulfur-containing polymers in both academia and industry. Compared to several sulfur-containing monomers that suffer from either restricted accessibility, low reactivity or tedious synthesis, sulfur dioxide, a well-known air pollutant, is a kind of easily obtained monomer with high reactivity and undergoes copolymerization with olefins and epoxides to produce degradable polysulfones and polysulfites. SO2-based polymer materials are of intense industrial and theoretical interest in terms of the large quantities of available monomers, facile polymerization, unique mechanism, and high performance of the resultant copolymers. In this review, we summarize the progress achieved in the copolymerization of SO2 with olefins and epoxides, mainly focusing on the monomer scope, mechanism, and properties of the resultant copolymers.

Graphical abstract: Sulfur-containing polymers derived from SO2: synthesis, properties, and applications

Article information

Article type
Review Article
Submitted
27 Mei 2022
Accepted
23 Ago 2022
First published
25 Ago 2022

Polym. Chem., 2022,13, 5282-5299

Sulfur-containing polymers derived from SO2: synthesis, properties, and applications

X. Zhu, X. Lu, H. Qi, Y. Wang and G. Wu, Polym. Chem., 2022, 13, 5282 DOI: 10.1039/D2PY00685E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements