Issue 62, 2021

Recent advances in palladium-catalyzed (hetero)annulation of C[double bond, length as m-dash]C bonds with ambiphilic organo(pseudo)halides

Abstract

Palladium has proven to be effective in catalyzing the (hetero)annulation of C[double bond, length as m-dash]C bonds with ambiphilic organo(pseudo)halides. Through the employment of appropriate ambiphilic coupling partners, efficient annulation of a variety of allenes, 1,3-dienes, strained alkenes, styrenes, and other C[double bond, length as m-dash]C bond variants can be achieved to provide direct access to numerous useful hetero- and carbocyclic scaffolds. In this Feature Article, we summarize palladium-catalyzed (hetero)annulation methods reported since 2005 (spanning just over 15 years) and discuss outstanding challenges in this area of study.

Graphical abstract: Recent advances in palladium-catalyzed (hetero)annulation of C [[double bond, length as m-dash]] C bonds with ambiphilic organo(pseudo)halides

Article information

Article type
Feature Article
Submitted
29 Mei 2021
Accepted
28 Jun 2021
First published
28 Jun 2021

Chem. Commun., 2021,57, 7610-7624

Recent advances in palladium-catalyzed (hetero)annulation of C[double bond, length as m-dash]C bonds with ambiphilic organo(pseudo)halides

H. Ni, P. Cooper and K. M. Engle, Chem. Commun., 2021, 57, 7610 DOI: 10.1039/D1CC02836G

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