Issue 6, 2020

Adsorption performance and mechanism of antibiotics from aqueous solutions on porous boron nitride–carbon nanosheets

Abstract

Antibiotics are a class of emerging contaminants with a potential threat to human and animal health. Chloramphenicol (CAP) and roxithromycin (ROX), which are extensively used, have attracted attention recently. In this work, two kinds of porous boron nitride–carbon nanosheets (BCNs and MBCNs) with different pore distributions were synthesized for the effective adsorption of antibiotics. The maximum adsorption capacity for CAP was 546.15 mg g−1, and the adsorption capacity for ROX was 575.68 mg g−1. It is worth noting that with the increase of molecular weight of antibiotics, huge molecules are blocked from entering micropores, and the adsorption capacity of BCNs decreases, indicating that a micropore-filling effect is the main mechanism of antibiotic adsorption on BCNs. In addition, hydrophobic interaction in chemical adsorption and electrostatic interaction were also important factors affecting the adsorption capacity of MBCN and BCN. The adsorbents were regenerated by simple high temperature calcination and excellent reusability was achieved after 6 cycles. Overall, the boron nitride–carbon nanosheets should be a good choice for the next generation of high performance adsorption materials.

Graphical abstract: Adsorption performance and mechanism of antibiotics from aqueous solutions on porous boron nitride–carbon nanosheets

Supplementary files

Article information

Article type
Paper
Submitted
12 Feb 2020
Accepted
03 Mei 2020
First published
04 Mei 2020

Environ. Sci.: Water Res. Technol., 2020,6, 1568-1575

Adsorption performance and mechanism of antibiotics from aqueous solutions on porous boron nitride–carbon nanosheets

G. Wang, Y. Zhang, S. Wang, Y. Wang, H. Song, S. Lv and C. Li, Environ. Sci.: Water Res. Technol., 2020, 6, 1568 DOI: 10.1039/D0EW00117A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements