Issue 86, 2020

Mobility of Lewis acids within the secondary coordination sphere: toward a model for cooperative substrate binding

Abstract

Distance dependence of appended Lewis acids in N2H4 binding and deprotonation was evaluated within a series of zinc complexes. Variation of spacer-length to a tethered trialkylborane Lewis acid revealed distinct preferences for binding and stabilization of the resulting deprotonated N2H3 unit.

Graphical abstract: Mobility of Lewis acids within the secondary coordination sphere: toward a model for cooperative substrate binding

Supplementary files

Article information

Article type
Communication
Submitted
27 Jul 2020
Accepted
16 Sep 2020
First published
05 Okt 2020

Chem. Commun., 2020,56, 13105-13108

Author version available

Mobility of Lewis acids within the secondary coordination sphere: toward a model for cooperative substrate binding

J. J. Kiernicki, E. E. Norwine, M. A. Lovasz, M. Zeller and N. K. Szymczak, Chem. Commun., 2020, 56, 13105 DOI: 10.1039/D0CC05121G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements