Lite Version|Standard version

To gain access to this content please
Log in via your home Institution.
Log in with your member or subscriber username and password.
Download

A new family of radical-bridged compounds, (Cp*2Co)[M2Cl4(dpq)] (M = Fe (1), Co (2), Zn (3)), (dpq = 2,3-di(2-pyridyl)-quinoxaline) is reported. Magnetic studies, DFT and ab initio calculations reveal strong antiferromagnetic metal–radical interactions with coupling constants of J = −213.1 and −218.8 cm−1 for 1 and 2, respectively.

Graphical abstract: Quinoxaline radical-bridged transition metal complexes with very strong antiferromagnetic coupling

Page: ^ Top