Issue 21, 2019

Metallopolymers cross-linked with self-assembled Ln4L4 cages

Abstract

Herein, we fabricated a hybrid PDVB-Ln4L4 metallopolymer using a vinyl functionalized lanthanide-organic tetrahedral cage as the cross-linking agent. Such a covalent embedding strategy not only tunes the morphology and porosity of the metallopolymer, but also improves the luminescence property of the lanthanide organic polyhedron. Potential application in lanthanide separation has also been demonstrated. This study provides a potential strategy for the immobilization of multinuclear lanthanide-organic edifices toward heterogeneous application.

Graphical abstract: Metallopolymers cross-linked with self-assembled Ln4L4 cages

Supplementary files

Article information

Article type
Communication
Submitted
20 Des 2018
Accepted
22 Feb 2019
First published
23 Feb 2019

Dalton Trans., 2019,48, 7080-7084

Metallopolymers cross-linked with self-assembled Ln4L4 cages

Q. Yan, L. Zhou, H. Zhou, Z. Wang, L. Cai, X. Guo, X. Sun and Q. Sun, Dalton Trans., 2019, 48, 7080 DOI: 10.1039/C8DT05015E

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