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Abstract | Cited by

Group 1 salts containing carbazolido NNN pincer ligands are precatalysts for the dehydrogenation of Me2NH·BH3. NMR monitoring and DOSY studies show a heavy dependence on the metal and solvent, allowing in some cases selective formation of dehydrogenation products consistent with hydrogen liberation.

Graphical abstract: Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes

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