Issue 5, 2017
From the journal:

Organic Chemistry Frontiers

5-Azadibenzo[a,g]corannulene†

V. M. Tsefrikas,a   A. K. Greenea  and  L. T. Scott ORCID logo *a  

* Corresponding authors

a Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467-3860, USA
E-mail: lawrence.scott@bc.edu

Abstract

5-Azadibenzo[a,g]corannulene, the first azacorannulene with a nitrogen on the rim, has been synthesized in seven steps from 4-bromoisoquinoline. The strained pyridine ring opens thermally to a polycyclic aromatic nitrile and hydrolytically to an amino aldehyde with the same polycyclic aromatic hydrocarbon framework.

Graphical abstract: 5-Azadibenzo[a,g]corannulene

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Article information

DOI
https://doi.org/10.1039/C6QO00831C
Article type
Research Article
Submitted
19 Des 2016
Accepted
09 Jan 2017
First published
19 Jan 2017

Org. Chem. Front., 2017,4, 688-698

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5-Azadibenzo[a,g]corannulene

V. M. Tsefrikas, A. K. Greene and L. T. Scott, Org. Chem. Front., 2017, 4, 688 DOI: 10.1039/C6QO00831C

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