Issue 45, 2015
From the journal:

RSC Advances

N-heterocyclic carbene-catalysed pentafluorophenylation of aldehydes†

Guang-Fen Du,ab   Fen Xing,b   Cheng-Zhi Gu,*b   Bin Dai*b  and  Lin Heb  

* Corresponding authors

a School of Chemical Engineering and Technology, Tianjin University. Tianjin 300072, China

b School of Chemistry and Chemical Engineering, Shihezi University, Xinjiang Uygur Autonomous Region, China
E-mail: gcz_tea@shzu.edu.cn, db_tea@shzu.edu.cn
Fax: +86-993-2057270

Abstract

N-heterocyclic carbenes have been utilized as highly efficient organocatalysts to catalyse multifluorophenylation of aldehydes with pentafluorophenyltrimethylsilane or bis(trimethylsilyl)tetrafluorobenzene to afford the corresponding fluorinated adducts in 49–99% yields.

Graphical abstract: N-heterocyclic carbene-catalysed pentafluorophenylation of aldehydes

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Article information

DOI
https://doi.org/10.1039/C5RA05487G
Article type
Communication
Submitted
27 Mac 2015
Accepted
13 Apr 2015
First published
13 Apr 2015

RSC Adv., 2015,5, 35513-35517

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N-heterocyclic carbene-catalysed pentafluorophenylation of aldehydes

G. Du, F. Xing, C. Gu, B. Dai and L. He, RSC Adv., 2015, 5, 35513 DOI: 10.1039/C5RA05487G

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