Issue 39, 2013

Bridging π-coordination of pyrrole and indole over a PdI–PdI bond

Abstract

π-Coordination of pyrrole or indole which lack a chelating functionality to a dinuclear PdI–PdI center is revealed. The dinuclear sandwich PdI–PdI complexes of pyrrole, N-methylpyrrole, or indole were synthesized and structurally characterized by X-ray crystallographic analysis. Indole employs the carbons of the six-membered ring in bridging π-coordination to a PdI–PdI center.

Graphical abstract: Bridging π-coordination of pyrrole and indole over a PdI–PdI bond

Supplementary files

Article information

Article type
Communication
Submitted
17 Okt 2012
Accepted
03 Des 2012
First published
20 Des 2012

Chem. Commun., 2013,49, 4310-4312

Bridging π-coordination of pyrrole and indole over a PdI–PdI bond

T. Murahashi, S. Kimura, K. Takase, S. Ogoshi and K. Yamamoto, Chem. Commun., 2013, 49, 4310 DOI: 10.1039/C2CC37554K

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