Issue 24, 2009

Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes

Abstract

The rhodium-catalyzed intermolecular asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes gave chiral allylicphosphine oxides substituted with vinylether and thioether moieties in high yields with high enantioselectivities.

Graphical abstract: Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes

Supplementary files

Article information

Article type
Communication
Submitted
16 Jan 2009
Accepted
17 Feb 2009
First published
13 Mac 2009

Chem. Commun., 2009, 3528-3530

Rhodium-catalyzed asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes

T. Kawamoto, S. Hirabayashi, X. Guo, T. Nishimura and T. Hayashi, Chem. Commun., 2009, 3528 DOI: 10.1039/B900976K

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