Issue 58, 2022

Catalytic machinery in motion: controlling catalysis via speed

Abstract

Three 3-component copper(I)-based slider-on-deck systems served as catalysts for a click reaction showing a higher catalytic activity with increasing sliding speed. Upon addition of brake stones, the motion of the resulting 4-component machinery was slowed and eventually stopped (on the NMR time scale) with the effect that catalysis was reduced or obstructed.

Graphical abstract: Catalytic machinery in motion: controlling catalysis via speed

Supplementary files

Article information

Article type
Communication
Submitted
05 Mei 2022
Accepted
20 Jun 2022
First published
21 Jun 2022
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2022,58, 8073-8076

Catalytic machinery in motion: controlling catalysis via speed

E. Elramadi, A. Ghosh, I. Valiyev, P. K. Biswas, T. Paululat and M. Schmittel, Chem. Commun., 2022, 58, 8073 DOI: 10.1039/D2CC02555H

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