Issue 6, 2021

Defect engineering and characterization of active sites for efficient electrocatalysis

Abstract

Electrocatalysis plays a decisive role in various energy-related applications. Engineering the active sites of electrocatalysts is an important aspect to promote their catalytic performance. In particular, defect engineering provides a feasible and efficient approach to improve the intrinsic activities and increase the number of active sites in electrocatalysts. In this review, recent investigations on defect engineering of a wide range of electrocatalysts such as metal-free carbon materials, transition metal oxides, transition metal dichalcogenides and metal–organic frameworks (MOFs) will be summarized. Different defect creation strategies will be outlined, for example, heteroatom doping and removal, plasma irradiation, hydrogenation, amorphization, phase transition and reduction treatment. In addition, we will overview the commonly used advanced characterization techniques that could confirm the existence and identify the detailed structures, types and concentration of defects in electrocatalysts. The defect characterization tools are beneficial for gaining an in-depth understanding of defects on electrocatalysis and thus could reveal the structure–performance relationship. Finally, the major challenges and future development directions on defect engineering of electrocatalysts will be discussed.

Graphical abstract: Defect engineering and characterization of active sites for efficient electrocatalysis

Article information

Article type
Review Article
Submitted
19 Des 2020
Accepted
16 Jan 2021
First published
18 Jan 2021

Nanoscale, 2021,13, 3327-3345

Defect engineering and characterization of active sites for efficient electrocatalysis

X. Yan, L. Zhuang, Z. Zhu and X. Yao, Nanoscale, 2021, 13, 3327 DOI: 10.1039/D0NR08976A

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