Issue 32, 2021

Exploring the structure–property schemes in anion–π systems of d-block metalates

Abstract

Anion–π based compounds, materials, and processes have gained significant interest due to the diversity of their aesthetic non-covalent synthons, and thanks to their significance in biological systems, catalytic processes, anion binding and sensing, or the supramolecular organization of hierarchical architectures. While systems based on typical inorganic anions or organic residues have been widely reviewed in recent years, those involving anionic d metal comlexes as the main components have been treated with a rather secondary interest. However, actively exploring the new systems of the latter type we have recognized systematic advances in the field. As a result, in the current review we describe the landscape that has recently emerged. Focusing on the established groups of π-acidic species, i.e. polycarbonitirles, polyazines, polyazine N-oxides, diimide derivatives, fluoroarenes, and nitroarenes, we explore and discuss anion–π crystal engineering together with the structure–property schemes important from the standpoint of charge transfer (CT) and electron transfer (ET), magnetism, luminescence, reactivity and catalysis, and the construction of core–shell crystalline composites.

Graphical abstract: Exploring the structure–property schemes in anion–π systems of d-block metalates

Article information

Article type
Perspective
Submitted
26 Mei 2021
Accepted
28 Jun 2021
First published
02 Jul 2021

Dalton Trans., 2021,50, 10999-11015

Exploring the structure–property schemes in anion–π systems of d-block metalates

E. Kuzniak-Glanowska, J. Kobylarczyk, K. Jedrzejowska, D. Glosz and R. Podgajny, Dalton Trans., 2021, 50, 10999 DOI: 10.1039/D1DT01713F

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