Issue 19, 2021

Synthesis of a new ATN-type zeolitic imidazolate framework through cooperative effects of N,N-dipropylformamide and n-butylamine

Abstract

A new zeolitic imidazolate framework (ZIF) was prepared using the cooperative effects of N,N-dipropylformamide and n-butylamine. ATN-[Zn(Im)2] is the first known example of a ZIF exhibiting a zeolitic ATN topology, which shows the flexible behavior of the framework. In addition, a known porous ZIF with a nog topology was obtained when using n-butylamine as the sole solvent, which suggests that a single organic amine can act as a template molecule for the synthesis of porous ZIFs.

Graphical abstract: Synthesis of a new ATN-type zeolitic imidazolate framework through cooperative effects of N,N-dipropylformamide and n-butylamine

Supplementary files

Article information

Article type
Communication
Submitted
01 Mac 2021
Accepted
13 Apr 2021
First published
13 Apr 2021

CrystEngComm, 2021,23, 3429-3433

Synthesis of a new ATN-type zeolitic imidazolate framework through cooperative effects of N,N-dipropylformamide and n-butylamine

Q. Meng, J. Wang, Q. Shi and J. Dong, CrystEngComm, 2021, 23, 3429 DOI: 10.1039/D1CE00287B

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