Purna Chandra Rao, Prabu Mani, Younghu Son, Jiyun Kim and Minyoung Yoon
Chem. Commun., 2021,57, 10158-10161
DOI:
10.1039/D1CC03721H,
Communication
We report epitaxially grown new two-dimensional metal–organic framework (MOF) thin films on a self-assembled monolayer (SAM). We fabricated these epitaxial thin-films using stepwise layer-by-layer seeding followed by solvothermal treatment. The MOF thin films exhibit ultrafast structural flexibility (through breathing) compared to their bulk samples upon uptake of organic guest molecules.