Issue 5, 2020

Effect of metal ion substitution on the catalytic activity of a pentanuclear metal complex

Abstract

A pentanuclear cobalt complex that consists of five cobalt ions and six bpp ligands (Co5, Hbpp = 3,5-bis(2-pyridyl)pyrazole) was synthesized and crystallographically characterized. Electrochemical measurements indicate that Co5 has multielectron transfer ability. We also found that Co5 reduces CO2 to CO under photoirradiation in the presence of a photosensitizer.

Graphical abstract: Effect of metal ion substitution on the catalytic activity of a pentanuclear metal complex

Supplementary files

Article information

Article type
Communication
Submitted
09 Des 2019
Accepted
06 Jan 2020
First published
07 Jan 2020

Dalton Trans., 2020,49, 1384-1387

Author version available

Effect of metal ion substitution on the catalytic activity of a pentanuclear metal complex

T. Akai, M. Kondo, S. K. Lee, H. Izu, T. Enomoto, M. Okamura, Y. Saga and S. Masaoka, Dalton Trans., 2020, 49, 1384 DOI: 10.1039/C9DT04684D

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