This website uses cookies to give you the best user experience. If you continue without changing your settings we'll assume you are happy to receive all RSC cookies. You can change your cookie settings by navigating to our Privacy and Cookies page and following the instructions. These instructions are also obtainable from the privacy link at the bottom of any RSC page.
Lite Version|Standard version
Home > Chemical Communications >
To gain access to this content please
Log in via your home Institution.
Log in with your member or subscriber username and password.
Download


Buy PDF Add PDF to Basket (£42.50*)
*Exclusive of taxes
This article contains 4 page(s)
Abstract | Cited by

We report the synthesis of a cyclic hexavanadate polyoxovanadate-alkoxide cluster, [VO(OC2H5)2]6, and its conversion, under solvothermal conditions, to an oxygen-deficient Lindqvist assembly, [V6O6(OC2H5)12]n (n = 1−, 0). This study presents insights into the mechanism of organo-functionalized polyoxovandate-alkoxide formation, namely identifying essential intermediates and the source of the central μ6-O2− ligand.

Graphical abstract: Mechanistic insights into polyoxometalate self-assembly in organic solvent: conversion of a cyclic polyoxovanadate-ethoxide to its Lindqvist congener

Page: ^ Top


Enter Keywords, author, title,reference, or DOI
Log in | Register