Issue 41, 2019

Exploring orientationally aligned anisotropic large spin molecules with unusual long-distance intermolecular ferromagnetic interactions

Abstract

Anisotropic magnetic clusters are interesting materials because magnetic anisotropy and spin state are important factors in their magnetic properties. Although long-distance magnetic interactions have been observed in several assemblies of anisotropic magnetic molecules, these interactions are small and observed at extremely low temperature (typically below 2 K). In this work, to assemble orientationally aligned anisotropic large spin metal oxo clusters, we managed to synthesize a {V3+Mn43+} cluster with a large-spin (ST = 9) ground state by utilizing an anisotropic lacunary polyoxometalate template. In the orientationally aligned clusters, unusual long-distance intermolecular ferromagnetic interactions were induced below 35 K under a small magnetic field (>0.01 T).

Graphical abstract: Exploring orientationally aligned anisotropic large spin molecules with unusual long-distance intermolecular ferromagnetic interactions

Supplementary files

Article information

Article type
Paper
Submitted
08 Feb 2019
Accepted
22 Mac 2019
First published
22 Mac 2019

J. Mater. Chem. C, 2019,7, 12918-12925

Author version available

Exploring orientationally aligned anisotropic large spin molecules with unusual long-distance intermolecular ferromagnetic interactions

T. Minato, Y. Ohata, K. Ishii, K. Yamaguchi, N. Mizuno and K. Suzuki, J. Mater. Chem. C, 2019, 7, 12918 DOI: 10.1039/C9TC00740G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements