Issue 19, 2019

Successive carbene insertion into 9-phenyl-9-borafluorene

Abstract

The reactions of 9-phenyl-9-borafluorene with trimethylsilyldiazomethane in a 1 : 1 and 1 : 2 stoichiometry furnished the corresponding BC5 and BC6 heterocycles via the formal insertion of one and two carbene units.

Graphical abstract: Successive carbene insertion into 9-phenyl-9-borafluorene

Supplementary files

Article information

Article type
Communication
Submitted
09 Mac 2019
Accepted
26 Mac 2019
First published
27 Mac 2019

Dalton Trans., 2019,48, 6319-6322

Author version available

Successive carbene insertion into 9-phenyl-9-borafluorene

T. A. Bartholome, K. R. Bluer and C. D. Martin, Dalton Trans., 2019, 48, 6319 DOI: 10.1039/C9DT01032G

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