Salen supported Al–O–CP and Ga–PCO complexes

Yanbo Mei; Jaap E. Borger; Dong-Jun Wu; Hansjörg Grützmacher

doi:10.1039/C9DT00485H

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Salen supported Al–O–CP and Ga–PCO complexes†

Yanbo Mei,^a Jaap E. Borger,

*^a Dong-Jun Wu^ab and Hansjörg Grützmacher

*^ab

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* Corresponding authors

^a Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog Weg 1, Hönggerberg, 8093 Zürich, Switzerland
E-mail: hgruetzmacher@ethz.ch, borger@inorg.chem.ethz.ch

^b Lehn Institute of Functional Materials (LIFM), School of Chemistry, Sun Yat-sen University, 510275 Guangzhou, China

Abstract

The first OCP adducts of aluminium and gallium are reported. The complexes are supported by sterically encumbered salen ligands and reveal a selective binding to O and P, respectively. Their reactivity with diazaphosphenium Lewis acids and N-heterocyclic carbene Lewis bases is described, in addition to cycloaddition reactions with s-tetrazines.

This article is part of the themed collection: Inorganic chemistry of the p-block elements

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DOI: https://doi.org/10.1039/C9DT00485H
Article type: Paper
Submitted: 31 Jan 2019
Accepted: 01 Mac 2019
First published: 12 Mac 2019
This article is Open Access

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Dalton Trans., 2019,48, 4370-4374

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Salen supported Al–O–CP and Ga–PCO complexes

Y. Mei, J. E. Borger, D. Wu and H. Grützmacher, Dalton Trans., 2019, 48, 4370 DOI: 10.1039/C9DT00485H

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Dalton Transactions

Salen supported Al–O–CP and Ga–PCO complexes†

Abstract

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Salen supported Al–O–CP and Ga–PCO complexes

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