Issue 14, 2018
From the journal:

Organic Chemistry Frontiers

Palladium-catalyzed reductive electrocarboxylation of allyl esters with carbon dioxide†

Ke-Jin Jiao,a   Zhao-Ming Li,a   Xue-Tao Xu, ORCID logo b   Li-Pu Zhang,b   Yi-Qian Li,b   Kun Zhangb  and  Tian-Sheng Mei ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China
E-mail: mei7900@sioc.ac.cn

b School of Chemical & Environmental Engineering, Wuyi University, Jiangmen, China

Abstract

Palladium-catalyzed regioselective electrocarboxylation of homostyrenyl acetates with CO2 has been successfully developed, providing α-aryl carboxylic acids with good selectivity and yield. In addition, the catalytic asymmetric carboxylation of cinnamyl acetate has been demonstrated, despite moderate enantioselectivity.

Graphical abstract: Palladium-catalyzed reductive electrocarboxylation of allyl esters with carbon dioxide

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Article information

DOI
https://doi.org/10.1039/C8QO00507A
Article type
Research Article
Submitted
23 May 2018
Accepted
15 Jun 2018
First published
22 Jun 2018

Org. Chem. Front., 2018,5, 2244-2248

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Palladium-catalyzed reductive electrocarboxylation of allyl esters with carbon dioxide

K. Jiao, Z. Li, X. Xu, L. Zhang, Y. Li, K. Zhang and T. Mei, Org. Chem. Front., 2018, 5, 2244 DOI: 10.1039/C8QO00507A

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