Issue 13, 2018

Highly efficient charge transfer through a double Z-scheme mechanism by a Cu-promoted MoO3/g-C3N4 hybrid nanocomposite with superior electrochemical and photocatalytic performance

Abstract

Herein, a novel Cu-MoO3/g-C3N4 hybrid nanocomposite was successfully synthesized by a two-step strategy of one-pot pyrolysis followed by the impregnation method. The structure, phase, morphology and electronic environment of MoO3, g-C3N4 and Cu in the composite were determined by various characterization methods. The oxygen vacancies of MoO3 were ascertained by UV-DRS, Raman, and XPS analysis. The formation of the heterostructure was characterised by electrochemical measurements. The photocatalytic performance of the composite was investigated by the water reduction reaction and the reduction of an important inorganic pollutant, Cr(VI). In the presence of Cu NPs, the H2 evolution of the MoO3/g-C3N4 hybrid was found to be 652 μmol h−1 with an apparent energy conversion efficiency of 13.46%, and up to 95% of Cr(VI) was reduced using citric acid as a hole scavenger. The remarkably enhanced photocatalytic performance was attributed to the combined effect of the double Z-scheme mechanism and defective MoO3. The in situ formation process of the MoO3/g-C3N4 hybrid followed a direct Z-scheme charge transfer by generating a great number of defects at the solid–solid interface, similar to that of a conductor, and offered low electrical resistance, whereas loading of Cu NPs built up an indirect Z-scheme charge transfer to establish the double Z-scheme charge transfer mechanism. This hybrid material produces a photocurrent density of 12.1 mA cm−2, in good agreement with the photocatalytic activity. This study highlights the facilitation effect of MoO3 due to oxygen vacancies and charge transfer through the double Z-scheme mechanism to open up a new window in the field of 2D nanostructured photocatalytic materials.

Graphical abstract: Highly efficient charge transfer through a double Z-scheme mechanism by a Cu-promoted MoO3/g-C3N4 hybrid nanocomposite with superior electrochemical and photocatalytic performance

Supplementary files

Article information

Article type
Paper
Submitted
05 Des 2017
Accepted
24 Feb 2018
First published
27 Feb 2018

Nanoscale, 2018,10, 5950-5964

Highly efficient charge transfer through a double Z-scheme mechanism by a Cu-promoted MoO3/g-C3N4 hybrid nanocomposite with superior electrochemical and photocatalytic performance

S. Patnaik, G. Swain and K. M. Parida, Nanoscale, 2018, 10, 5950 DOI: 10.1039/C7NR09049H

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