Issue 21, 2018

Pd nanoparticles/polyoxometalate–ionic liquid composites on SiO2 as multifunctional catalysts for efficient production of ketones from diaryl ethers

Abstract

The high stability of C–O bonds in diaryl ethers limits the valorization of lignin. Herein, reductive hydrolysis of C–O bonds in diaryl ethers was achieved over Pd nanoparticle/polyoxometalate–ionic liquid composite supported on SiO2 (Pd/H2[POM-IL]@SiO2) in water, selectively yielding ketones free from their alcohol counterparts in unprecedentedly high yields (>80%).

Graphical abstract: Pd nanoparticles/polyoxometalate–ionic liquid composites on SiO2 as multifunctional catalysts for efficient production of ketones from diaryl ethers

Supplementary files

Article information

Article type
Communication
Submitted
21 Ago 2018
Accepted
02 Okt 2018
First published
04 Okt 2018

Green Chem., 2018,20, 4865-4869

Pd nanoparticles/polyoxometalate–ionic liquid composites on SiO2 as multifunctional catalysts for efficient production of ketones from diaryl ethers

Z. Zhang, M. Liu, J. Song, H. Liu, Z. Xie, S. Liu, Q. Meng, P. Zhang and B. Han, Green Chem., 2018, 20, 4865 DOI: 10.1039/C8GC02659A

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