Issue 73, 2018

Synthesis of uranium-in-cryptand complexes

Abstract

The facile encapsulation of U(III) and La(III) by 2.2.2-cryptand (crypt) using simple starting materials is described. Addition of crypt to UI3 and LaCl3 forms the crystallographically-characterizable complexes, [U(crypt)I2]I and [La(crypt)Cl2]Cl. In the presence of water, the U(III)-aquo adducts, [U(crypt)I(OH2)][I]2 and [U(crypt)I(OH2)][I][BPh4], can be isolated.

Graphical abstract: Synthesis of uranium-in-cryptand complexes

Supplementary files

Article information

Article type
Communication
Submitted
03 Jul 2018
Accepted
15 Ago 2018
First published
15 Ago 2018

Chem. Commun., 2018,54, 10272-10275

Author version available

Synthesis of uranium-in-cryptand complexes

D. N. Huh, C. J. Windorff, J. W. Ziller and W. J. Evans, Chem. Commun., 2018, 54, 10272 DOI: 10.1039/C8CC05341C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements