Issue 73, 2018

The “Wanderlust” of Me3Si groups in rare-earth triple-decker complexes: a combined experimental and computational study

Abstract

The migration of Me3Si groups (“Wanderlust”) in rare-earth triple-decker sandwich complexes of the type Ln2(COT′′)3 (COT′′ = bis(trimethylsilyl)cyclooctatetraenyl) has been elucidated by a combined experimental and computational study. For the first time, two isomers of a Ln2(COT′′)3 triple-decker have been isolated and characterized in the case of Y2(COT′′)3.

Graphical abstract: The “Wanderlust” of Me3Si groups in rare-earth triple-decker complexes: a combined experimental and computational study

Supplementary files

Article information

Article type
Communication
Submitted
02 Jul 2018
Accepted
20 Ago 2018
First published
21 Ago 2018

Chem. Commun., 2018,54, 10280-10283

The “Wanderlust” of Me3Si groups in rare-earth triple-decker complexes: a combined experimental and computational study

V. Lorenz, P. Liebing, A. Bathelier, F. Engelhardt, L. Maron, L. Hilfert, S. Busse and F. T. Edelmann, Chem. Commun., 2018, 54, 10280 DOI: 10.1039/C8CC05317K

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