Issue 77, 2018

Impacts of oxo interactions within actinyl metal organic materials: highlight on thermal expansion behaviour

Abstract

Physical properties of actinyl materials are influenced by the presence of oxo functional groups. Herein, we report large thermal expansion coefficients for a uranyl metal organic nanotube that switch from positive to negative upon dehydration. Different behaviour is observed in the neptunyl system due to variations in the oxo interactions.

Graphical abstract: Impacts of oxo interactions within actinyl metal organic materials: highlight on thermal expansion behaviour

Supplementary files

Article information

Article type
Communication
Submitted
29 Jun 2018
Accepted
17 Ago 2018
First published
17 Ago 2018

Chem. Commun., 2018,54, 10828-10831

Author version available

Impacts of oxo interactions within actinyl metal organic materials: highlight on thermal expansion behaviour

M. K. Payne, M. M. Pyrch, M. Jubinsky, M. C. Basile and T. Z. Forbes, Chem. Commun., 2018, 54, 10828 DOI: 10.1039/C8CC05240A

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