Issue 63, 2018
From the journal:

Chemical Communications

Highly Lewis acidic cationic alkaline earth metal complexes†

Jürgen Pahl, ORCID logo a   Steffen Brand, ORCID logo a   Holger Elsen ORCID logo a  and  Sjoerd Harder ORCID logo *a  

* Corresponding authors

a Inorganic and Organometallic Chemistry, University Erlangen-Nürnberg, Egerlandstrasse 1, 91058 Erlangen, Germany
E-mail: sjoerd.harder@fau.de

Abstract

Cationic Lewis base-free β-diketiminate (BDI) complexes of Mg and Ca have been isolated as their B(C6F5)4− salts. The cation (BDI)Mg+ shows an extraordinarily strong Lewis acidity that can compete with strong Lewis acids like B(C6F5)3 and (BDI)AlMe+. Its highly electrophilic nature is exemplified by isolation of an 3-hexyne adduct.

Graphical abstract: Highly Lewis acidic cationic alkaline earth metal complexes

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Article information

DOI
https://doi.org/10.1039/C8CC04083D
Article type
Communication
Submitted
22 Mei 2018
Accepted
01 Jun 2018
First published
01 Jun 2018

Chem. Commun., 2018,54, 8685-8688

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Highly Lewis acidic cationic alkaline earth metal complexes

J. Pahl, S. Brand, H. Elsen and S. Harder, Chem. Commun., 2018, 54, 8685 DOI: 10.1039/C8CC04083D

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